Over the past couple of years, Paul Godin has been leading an effort in my group to understand the warming potential of the ancient martian atmosphere, above he shows experimentally-derived values for CO2-CH4 CIA as measured using the Canadian Light Source. He just submitted a paper on this topic which is now under review.
By Dr. Paul Godin
We’ve discussed in previous blogposts about our group’s effort to better constrain the early Mars atmosphere by taking measurements at the Canadian Light Source (http://york-pvl.blogspot.com/2018/11/searching-for-liquid-water-on-mars-at.html and http://york-pvl.blogspot.com/2019/04/the-continuing-adventures-at-canadian.html). As a quick summary, geological features on the surface of present-day Mars imply that there was once liquid water on the surface. To have liquid water on the surface, a sufficiently strongly absorbing atmosphere is required to produce enough of a greenhouse effect to warm the surface above freezing temperatures. Since most ancient Mars modeling suggest that Mars did not have a dense atmosphere, the remaining possibility is that the gas composition of an ancient Mars atmosphere could be strongly absorbing. One idea was collision induced absorption (CIA) between CO2 and H2 molecules, and CO2 and CH4 molecules, could provide enough absorption to warm ancient Mars. The goal of the CLS trips was to experimentally measure this CIA effect to determine if it was as strong as predicted.