Introducing our newest addition to PVL, Dr. Paul Godin who comes to us from the University of Toronto! Paul specialized in laboratory-based research in the atmospheric sciences, and will now apply that strong base to the atmospheres of other worlds. The image above is from the Intergovernmental Panel on Climate Change and depicts
IR absorptions both of the
atmosphere (top) and of select molecules (bottom).
by Paul Godin
Hello World! My name is Paul and I’m the newest member of
the PVL, so I should probably introduce myself, eh? I just completed my PhD in
physics at the University of Toronto studying the radiative impacts of several
chemicals on the atmosphere, using a metric known as a global warming potential
(GWP). A GWP is the measure of the radiative forcing of a pulse emission of one
kilogram of gas over a defined period of time (commonly taken to be 100 years),
relative to an identical pulse emission of carbon dioxide. Radiative forcing is
defined as the net change of radiation at the tropopause; positive radiative
forcing means more radiation directed towards the surface (leading to higher
surface temperatures), whereas negative radiative forcing corresponds to a net
cooling effect.
The radiative forcing of a molecule depends largely on two
main factors, the absorption spectrum of the molecule and the absorption
profile of the atmosphere. The absorption spectrum of a molecule is a result of
the quantum mechanical interactions within the molecule, thus the structure and
composition of a molecule will dictate at what wavelengths of light the
molecule can absorb. The atmospheric absorption spectrum is the sum of the
absorption spectra of all the species present in the atmosphere (largely made
up of water, carbon dioxide, ozone, nitrogen, etc.). The atmospheric absorption
spectrum for the infrared (wavelengths associated with outgoing radiation) is
shown in the top half of the figure at the start of this article. As can be seen, the atmosphere
normally absorbs a significant fraction of outgoing radiation, but also has a
region where it doesn’t naturally absorb radiation (8-13 μm),
which is known as the atmospheric window. This is great for life on Earth; we
need to trap some of the radiation to keep the planet from being frozen, but also
allows enough heat escape that we don’t turn in to a furnace (i.e. Venus).